Hypercarbon chemistry /
Hypercarbon chemistry /
by George A. Olah [and others].
- 2nd ed.
- Hoboken, N.J. : J. WIley & Sons, ©2011.
- 1 online resource
Includes bibliographical references and index.
Introduction: general aspects -- Carbon-bridged (associated) metal alkyls -- Carboranes and metallacarboranes -- Mixed metal-carbon clusters and metal carbides -- Hypercoordinate carbocations and their borane analogs -- Reactions involving hypercarbon intermediates -- Conclusions and outlook.
The essential new edition of the book that put hypercarbon chemistry on the map. A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks. Despite the firmly established tetravalency, carbon can bond simultaneously to five or more other atoms. "Hypercarbon" bonding permeates much organic, inorganic and organometallic chemistry, and the book serves as the compendium for this phenomenon. Copious diagrams illustrate the rich variety of hypercarbon structures now known, and patterns therein. Individual chapters deal with specific categories of compound (e.g. organometallics, carboranes, carbocations) or transformations that proceed through transient hypercarbon species, detailing fundamental chemistry, including reactivity, selectivity, stereochemistry, mechanistic factors and more.
9781118016466 1118016467 9780470935682 0470935685 9781118016442 1118016440 1118016459 9781118016459
9786613175625
10.1002/9781118016466 Wiley InterScience http://www3.interscience.wiley.com
Carbonium ions.
Organometallic chemistry.
SCIENCE--Chemistry--Organic.
Carbonium ions.
Organometallic chemistry.
Electronic books.
Electronic books.
QD305.C3 / H97 2011eb
547.01
Includes bibliographical references and index.
Introduction: general aspects -- Carbon-bridged (associated) metal alkyls -- Carboranes and metallacarboranes -- Mixed metal-carbon clusters and metal carbides -- Hypercoordinate carbocations and their borane analogs -- Reactions involving hypercarbon intermediates -- Conclusions and outlook.
The essential new edition of the book that put hypercarbon chemistry on the map. A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks. Despite the firmly established tetravalency, carbon can bond simultaneously to five or more other atoms. "Hypercarbon" bonding permeates much organic, inorganic and organometallic chemistry, and the book serves as the compendium for this phenomenon. Copious diagrams illustrate the rich variety of hypercarbon structures now known, and patterns therein. Individual chapters deal with specific categories of compound (e.g. organometallics, carboranes, carbocations) or transformations that proceed through transient hypercarbon species, detailing fundamental chemistry, including reactivity, selectivity, stereochemistry, mechanistic factors and more.
9781118016466 1118016467 9780470935682 0470935685 9781118016442 1118016440 1118016459 9781118016459
9786613175625
10.1002/9781118016466 Wiley InterScience http://www3.interscience.wiley.com
Carbonium ions.
Organometallic chemistry.
SCIENCE--Chemistry--Organic.
Carbonium ions.
Organometallic chemistry.
Electronic books.
Electronic books.
QD305.C3 / H97 2011eb
547.01